When they get older, male Pekins will most likely have a curled feather in the end of their tails. With pekin ducklings it is impossible to tell the gender until they get older, though sometimes the females will try to quack sooner than the males, as well as they can be noisier then males as ducklings.
The boys have a dark orange/yellow beak and the girls have more of a pink/orange colored beak when little.